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A Resonance Tunable and Durable Lspr Nano-Particle Sensor: Al2O3 Capped Silver Nano-Disks

By Daryoush Mortazavi, Abbas Z. Kouzani, and Kristy C. Vernon
Progress In Electromagnetics Research, Vol. 130, 429-446, 2012


Localized surface plasmon resonance (LSPR) biosensors are employed to detect target biomolecules which have particular resonance wavelengths. Accordingly, tunability of the LSPR wavelength is essential in designing LSPR devices. LSPR devices employing silver nano-particles present better efficiencies than those using other noble metals such as gold; however, silver nano-particles are easily oxidized when they come in contact with liquids, which is inevitable in biosensing applications. To attain both durability and tunabilty in a LSPR biosensor, this paper proposes alumina (AL2O3) capped silver nano-disks. It is shown that through controlling the thickness of the cap, the LSPR resonance frequency can be finely tuned over a wide range; and moreover, the cap protects silver nano-particles from oxidation and high temperature.


Daryoush Mortazavi, Abbas Z. Kouzani, and Kristy C. Vernon, "A Resonance Tunable and Durable Lspr Nano-Particle Sensor: Al2O3 Capped Silver Nano-Disks," Progress In Electromagnetics Research, Vol. 130, 429-446, 2012.


    1. Ishimaru, A., S. Jaruwatanadilok, and Y. Kuga, "Generalized surface plasmon resonance sensors using metamaterials and negative index materials," Progress In Electromagnetic Research, Vol. 51, 139-152, 2005.

    2. Han, L., S. Chen, A. Schulzgen, Y. Zeng, F. Song, J.-G. Tian, and N. Peyghambarian, "Calculation and optimization of electromagnetic resonances and local intensity enhancements for plasmon metamaterials with sub-wavelength double-slots," Progress In Electromagnetic Research, Vol. 113, 161-177, 2011.

    3. Cao, P., X. Zhang, W.-J. Kong, L. Cheng, and H. Zhang, "Super resolution enhancement for the superlens with anti-reflection and phase control coatings via surface plasmons modes of asymmetric structure," Progress In Electromagnetic Research, Vol. 119, 191-206, 2011.

    4. Liu, X., J. Lin, T. F. Jiang, Z. F. Zhu, Q. Q. Zhan, J. Qian, and S. He, "Surface plasmon properties of hollow AuAg alloyed triangular nanoboxes and its applications in SERS imaging and potential drug delivery ," Progress In Electromagnetic Research, Vol. 128, 35-53, 2012.

    5. Zhao, J., K. Li, F. Kong, and L.-G. Du, "Enhancement of blue light emission using surface plasmons coupling with quantum wells," Progress In Electromagnetic Research, Vol. 108, 293-306, 2010.

    6. Nath, N. and A. Chilkoti, "A colorimetric gold nanoparticle sensor to interrogate biomolecular interactions in real time on a surface," Analytical Chemistry, Vol. 74, 2002.

    7. Samantha, S. and J. Bokatzian, Surface plasmon resonance: Principles and applications, Graduate Student Seminar Series, Department of Chemistry, University of Alabama, 2008.

    8. Homola, J., et al., "Multi-analyte surface plasmon resonance biosensing," Methods, Vol. 37, 26-36, 2005.

    9. Davis, T. J., K. C. Vernon, and D. E. Gómez, "Designing plasmonic systems using optical coupling between nanoparticles," Physical Review B, Vol. 79, 155423-155432, 2009.

    10. Mortazavi, D., A. Z. Kouzani, and A. Kaynak, Nano-plasmonic biosensors: A review, IEEE/ICME International Conference on Complex Medical Engineering (CME), ICMEA'11, Harbin, China, 2011.

    11. Haynes, C. L., A. D. McFarland, and R. P. van Duyne, "Surface-enhanced Raman spectroscopy," Analytical Chemistry, Vol. 77, 339-346, Sep. 1, 2005.

    12. Maier, S. A. and H. A. Atwater, "Plasmonics: Localization and guiding of electromagnetic energy in metal/dielectric structures," J. of Applied Physics, Vol. 98, 2005.

    13. Link, S. and M. A. El-Sayed, "Spectral properties and relaxation dynamics of surface plasmon electronic oscillations in gold and silver nanodots and nanorods ," J. Physical Chemistry B, Vol. 103, 8410-8426, 1999.

    14. Zhang, S., et al., "Substrate-induced fano resonances of a plasmonic nanocube: A route to increased-sensitivity localized surface Plasmon resonance sensors revealed ," Nano Letters, Vol. 11, 1657-1663, 2011.

    15. Stuart, D. A., et al., "Glucose sensing using near-infrared surface-enhanced raman spectroscopy: Gold surfaces, 10-day stability, and improved accuracy," Analytical Chemistry, Vol. 77, 4013-4019, 2005.

    16. Sekhon, J. S. and S. S. Verma, "Rational selection of nanorod plasmons: Material, size, and shape dependence mechanism for optical sensors," Plasmonics, 1-7, 2012.

    17. Lantiat, D., et al., "Evidence for capping-layer effects on the morphology and plasmon excitation of Ag nanoparticles," J. of Applied Physics, Vol. 102, 2007.

    18. Mortazavi, D., A. Z. Kouzani, A. Kaynak, and W. Duan, "Developing LSPR design guidlines," Progress In Electromagnetic Research, Vol. 126, 203-235, 2012.

    19. Niu, J., et al., "Graphene induced tunability of the surface plasmon resonance," Applied Physics Letters, Vol. 100, 2012.

    20. Elert, G., Resistivity of aluminum oxide, The Physics Factbook, E. Huang (ed.), http://hypertextbook.com/facts/2006/EuniceHuang.shtml, 2006.

    21. Whitney, A. V., et al., "Localized surface plasmon resonance nanosensor: A high-resolution distance-dependence study using atomic layer deposition," J. Physical Chemistry B, Vol. 109, 20522-20528, 2005.

    22. Zhang, X., et al., "Ultrastable substrates for surface-enhanced Raman spectroscopy: Al2O3 overlayers fabricated by atomic layer deposition yield improved anthrax biomarker detection," American Chemical Society, Vol. 128, 10304-10309, 2006.

    23. Mortazavi, D., A. Z. Kouzani, and A. Kaynak, "Investigating nanoparticle-substrate interaction in LSPR biosensing using the image-charge theory," EMBC'12, San Diego, USA, Aug. 2012.

    24. Davis, T. J., D. E. Gomez, and K. C. Vernon, "Simple model for the hybridization of surface plasmon resonances in metallic nanoparticles," Nano Letters, Vol. 10, 2618-2625, 2010.

    25. Vernon, K. C., et al., "Influence of particle-substrate interaction on localized plasmon resonances," Nano Letters, Vol. 10, 2080-2086, 2010.

    26. Gómez, D. E., K. C. Vernon, and T. J. Davis, "Symmetry effects on the optical coupling between plasmonic nanoparticles with applications to hierarchical structures," Physical Review B, Vol. 81, 075414-423, 2010.

    27. Mishchenko, M. I., L. D. Travis, and J. W. Hovenier, Light Scattering by Nonspherical Particles: Theory, Measurements, and Applications, Academic Press, 2000.

    28. Yamaguchi, T., S. Yoshida, and A. Kinbara, "Optical effect of the substrate on the anomalous absorption of aggregated silver films," Thin Solid Films, Vol. 21, 173-187, 1974.

    29. Lee, B., et al., "Review on subwavelength confinement of light with plasmonics," J. of Modern Optics, Vol. 57, 1479-1497, 2010.

    30. Petryayeva, E. and U. J. Krull, "Localized surface plasmon resonance: Nanostructures, bioassays and biosensing --- A review," Analytica Chimica Acta, Vol. 706, 8-24, 2011.

    31. Taflove, A., Computational Electrodynamics: The Finite-difference Time-domain Method, Artech House, London, Boston, 1995.

    32. Vaccari, A., A., A. Cala' Lesina, L. Cristoforetti, and R. Pontalti, "Parallel implementation of a 3D subgriding FDTD algorithm for large simulations," Progress In Electromagnetic Research, Vol. 120, 263-292, 2011.

    33. Lee, K. H., I. Ahmed, R. S. M. Goh, E. H. Khoo, E. P. Li, and T. G. G. Hung, "Implementation of the FDTD method based on Lorentz-Drude dispersive model on GPU fro plasmonics applications ," Progress In Electromagnetic Research, Vol. 116, 441-456, 2011.

    34. Singh, R., et al., "Sharp fano resonances in THz metamaterials," Optics Express, Vol. 19, 6312-6319, 2011.

    35. Zhang, W., B. Gallinet, and O. J. F. Martin, "Symmetry and selection rules for localized surface plasmon resonances in nanostructures," Physical Review B, Vol. 81, 233407-233410, 2010.

    36. Fan, X., et al., "Sensitive optical biosensors for unlabeled targets: A review," Analytica Chimica Acta, Vol. 620, 8-26, 2008.

    37. Lahav, A., M. Auslender, and I. Abdulhalim, "Sensitivity enhancement of guided-wave surface-plasmon resonance sensors," Optics Letters, Vol. 33, 2539-2541, 2008.

    38. Shalabney, A. and I. Abdulhalim, "Sensitivity-enhancement methods for surface plasmon sensors," Laser & Photonics Reviews, Vol. 5, 571-606, 2011.

    39. Kang, M., et al., "Protein capture in silica nanotube membrane 3-D microwell arrays," Anal. Chem., Vol. 77, 6243-6249, 2005.

    40. Luo, Z., T. Suyama, X. Xu, and Y. Okuno, "A grating-based plasmon biosensor with high resolution ," Progress In Electromagnetic Research, Vol. 118, 527-539, 2011.

    41. Lide, D. R., CRC Handbook of Chemistry and Physics, 87th Ed., Taylor and Francis Group, Boca Raton, FL, 2007.

    42. Jin, Y., D. Gao, and L. Gao, "Plasmonic resonant light scattering by a cylinder with radial anisotropy," Progress In Electromagnetic Research, Vol. 106, 335-347, 2010.

    43. Kuwata, H., et al., "Resonant light scattering from metal nanoparticles: Practical analysis beyond Rayleigh approximation," Applied Physics Letters, Vol. 83, 4625-4627, 2003.

    44. Mortazavi, D., et al., Plasmon eignevalues as a function of nano-spheroids size and elongation , Proceeding of ICMEA'12, Kobe, Japan, Jul. 2012.